Patti Smith Reacts To Taylor Swift Name-Dropping Her On Tortured Poets Department

On her new album’s title track, The Tortured Poets Department, Taylor sings: “I laughed in your face and said, ‘You’re not Dylan Thomas / I’m not Patti Smith / This ain’t the Chelsea Hotel / We’re modern idiots’.”

In response, the New York counterculture icon posted a black-and whit- Instagram photo of herself smiling behind a copy of Dylan Thomas’ Portrait Of The Artist As A Young Dog.

“This is saying I was moved to be mentioned in the company of the great Welsh poet Dylan Thomas,” she captioned the post. “Thank you, Taylor.”

While Patti and Taylor may seem worlds apart, the Horses artist talked about sympathising with the Reputation singer in a 2019 profile for the New York Times.

Asked if artists like Taylor should be more politically engaged in the era of Donald Trump, Patti said: “She’s a pop star who’s under tremendous scrutiny all the time, and one can’t imagine what that’s like. It’s unbelievable to not be able to go anywhere, do anything, have messy hair.”

“And I’m sure that she’s trying to do something good,” the singer and former muse of Robert Mapplethorpe went on.

“She’s not trying to do something bad. And if it influences some of her avid fans to open up their thoughts, what does it matter?”

Last month, Patti gave her seal of approval to another modern pop star, when she co-signed Dua Lipa’s spot on Time’s annual list of 100 Most Influential People.

Share Button

Kay Burley Calls Minister Out For Side-Stepping Questions Over ‘Disgraceful’ Mark Menzies Saga

Kay Burley cornered a minister over the Conservatives’ handling of the saga around former Tory Mark Menzies in an awkward Sky News clash on Monday.

Menzies resigned from the party on Sunday and announced he would not be standing at the next general election, days after allegations he had misused campaign funds emerged.

He denied all claims against him. A Tory Party investigation found he had not misused funds because he had taken money from a group outside of the main Conservative remit.

However, the Sky News presenter still pressed foreign minister Andrew Mitchell over the messy incident.

Burley asked: “What most offended you about [Mark Menzies]′ actions?

“Was it the misuse of funds, was it his questionable behaviour over many years or was it [him] asking a member of his team to go to a potential crime scene, with a bag load of cash, where she was already told, ‘bad men are inside’?”

Mitchell replied: “I’ve been in Washington until yesterday doing my job as the minister for international development.”

Burley refused to take that as answer, only for Mitchell to say: “I’m not fully conversant with all the details.”

“Well, you should be,” the presenter noted.

Mitchell continued: “What I am clear about is that the Conservative Party has properly investigated this matter.

“It’s done it in a timely way, which respects the rights of all parties, lessons will be learnt.”

Burley laughed and said: “What does that mean?”

According to The Times – which first broke the story – the Tories had been aware of the allegations for three months, but had not taken any action.

Burley asked again: “Are you more offended by the funds or the fact that a junior member of his team was told to go with a bag-load of cash where she had been told bad men were inside? That’s disgraceful.”

“I don’t think his actions were those one has the right to expect from a member of parliament and that is why he no longer has the whip and is no longer a member of the Conservative Party,” Mitchell said.

Burley pushed: “Should he step down altogether or are you quite relieved that he’s waiting until the next election so there’s not another by-election?”

Mitchell said that was not a matter for the Tories anymore.

Burley said: “So you’re very happy that the party have handled this in exactly the right way?”

Mitchell just replied that the party has handled it in a “way that handles the rights of the individuals” involved, and that he does not “criticise the party over the speed with which it handled this”.

“Would you expect a Conservative aide to have to behave in this manner, taking a bag load of cash to a place that isn’t safe?” Burley asked again.

Mitchell replied: “That is why we are looking at the issue of a whistleblowers’ rights, and doing a retraining of those in the Conservative Association to make sure this doesn’t happen again.”

Share Button

Sabrina Carpenter Ends Coachella Set With Racy Shout-Out For Barry Keoghan

Sabrina ended her performance on Saturday with a rendition of her hit Nonsense – including a rewritten version of the song’s outro with new lyrics that reference Barry’s film Saltburn.

Made his knees so weak he had to spread mine, he’s drinking my bath water like it’s red wine,” she said.

The new lyric, of course, references one of Barry’s most iconic Saltburn scenes, in which his character Oliver Quick drinks the remnants of his friend Felix Catton’s bath water from a drain, after spotting him masturbating in the tub.

Sabrina and Barry were first rumoured to be an item at the end of last year.

Back in January, it was reported in the press that they had been planning to “hard launch” their relationship at the Golden Globes, where he was a nominee.

Before his rumoured romance with Sabrina, Barry was in a relationship with orthodontic therapist Alyson Kierans, with whom he shares a one-year-old son, Brando.

As well as Barry-related lyrics, Sabrina’s rewritten Nonsense outro ended: “Coachella see you back here when I headline.”

Share Button

Israel’s Strike On Iran Prolongs An Excruciating Limbo For Palestinians

As open fighting between two of the Middle East’s best-armed players worsens, more than a million Palestinian lives hang in the balance.

Israel on Thursday attacked Iran, in retaliation for an April 13 attack from Iranian drones and missiles, which was itself a retaliation for the Israeli bombing of an Iranian consulate on April 1.

Iran downplayed the significance of the strike, with state media saying it caused no major damage. The US, Israel’s military lifeline, did so too. Secretary of State Antony Blinken told reporters the Biden administration “has not been involved in any offensive operations” and seeks “de-escalation and [to] avoi[d] a larger conflict.”

The state-on-state strikes between Israel and Iran, a prospect that risks sparking an all-out war, are “over,” a regional government source argued to CNN after the latest Israeli strike, saying Iran was unlikely to respond. Multiple national security analysts agreed Israel’s move seemed carefully calibrated, ostensibly in line with the priorities of the US and of anxious neighbouring countries.

Still, the two countries indisputably moved closer to head-on conflict through their unprecedented tit-for-tat in recent weeks. “The US will celebrate a small success. But the spiral is still spinning downward: rules are being rewritten on the battlefield,” wrote Emile Hokayem, an analyst at the International institute for Strategic Studies, a think tank, on X.

As the potential for extremely costly miscalculation persists, questions remain open: Is this the full extent of Israel’s response to Iran? Will the two now continue their longstanding bids to weaken each other through clashes elsewhere, perhaps in already bruised Lebanon?

It’s hard to see how the spiral stops until another question is answered: What about Palestine?

Rafah, the town in southern Gaza where nearly 1.5 million Palestinians are sheltering, is the only section of the strip Israel has yet to invade its sweeping, hugely controversial campaign.

Israeli Prime Minister Benjamin Netanyahu says an attack on Rafah is vital to shield Israel from the Gaza-based militant group Hamas.

Washington says it cannot support that plan without a serious strategy for evacuating and helping civilians — a strategy Israel has yet to provide, the White House confirmed in a Thursday statement, after a high-level meeting between US and Israeli officials.

The Biden administration is casting its attempt to temper the Rafah operation as distinct from its bid to prevent an Israel-Iran war. But to other observers, it’s impossible to separate the two. President Joe Biden is simultaneously the only outside world leader with the power to force a change in course for Israel, and a longtime ally of Israeli leadership who may be loath to seek their restraint, particularly as the country is in active conflict with Iran.

Calling the resurgent Israeli-Palestinian conflict “the beating heart of this increasingly regional problem,” Monica Marks, a professor at New York University’s Abu Dhabi campus, told HuffPost on Friday: “The thing to watch for … is whether Netanyahu bought more wiggle room on the Biden administration’s expectation for Israel to make humanitarian plans regarding Rafah’s civilians.”

Israel’s actions suggest it continues to see moving on Rafah as inevitable. Sources told multiple media outlets preparations had already begun, with leaflets directing civilians to flee already printed and scheduled to be dropped on Monday, though Israeli sourced told CNN the Iran attack had caused a delay. On Monday night, Israeli defence minister Yoav Gallant held a military briefing on Rafah, and at Thursday’s US-Israeli summit, both sides agreed discussions about the offensive would continue.

The prolonged uncertainty is chilling for civilians in Rafah, which constitutes the last remotely functional section of Gaza. The vast majority of Palestinians are barred from leaving the territory for neighbouring Egypt.

Describing widespread anticipation of an Israeli ground invasion and “constant anxiety due to the ongoing airstrikes,” Ghada Alhaddad told HuffPost she has witnessed panicked civilians Rafah to try to return to other parts of Gaza, only to find little but wreckage there.

“The lingering sense of fear has left many unsure of where to go next,” said Alhaddad, who works for the charity Oxfam.

Displaced Palestinian children line up to receive food in Rafah on April 19, 2024.
Displaced Palestinian children line up to receive food in Rafah on April 19, 2024.

MOHAMMED ABED via Getty Images

As decision-makers in governments remain vague about their plans, the outside players helping Palestinians survive amid food shortages, bombardment and displacement fear the worst. Representatives of five major aid groups told HuffPost this week that even the meager support they are able to currently provide to Palestinians would plummet if Rafah is attacked, and they have yet to see either realistic plans for addressing the civilian toll of an assault or effective Israeli steps to bolster humanitarian relief for Gaza. Biden has pushed harder for increased aid since an Israeli attack killed seven relief workers on April 1.

“The conditions for us to provide an adequate humanitarian response are not there right now – let alone if the conditions become more challenging because we don’t have access to Rafah and people are put into a catastrophic situation,” said Tess Ingram, a UNICEF spokesperson who returned from a visit to Gaza on Monday.

Scott Paul of Oxfam America told HuffPost he and his colleagues fear geopolitical discussions will distract from measures to protect Palestinians, at least 34,000 of whom have been killed since Israel’s offensive began.

“There’s a widespread concern that it will be difficult to deescalate regional tensions and keep the focus on a population on the brink of famine,” Paul said. “We’re very worried that Palestinians will get the short end of the stick.”

Seeking anonymity to discuss sensitive internal deliberations, a source at a humanitarian organisation said they had little faith in the US to moderate Israel’s approach to Rafah.

“You just can’t look to the Biden administration for signals, because the Israelis have proven time and again that just because assurances are given to the US side doesn’t mean they’re going to be held to them,” said the source. They described aid groups as in “purgatory” as conditions for Palestinians decline and as the trajectory of the conflict remains unclear, and said Israel is deploying “a purposeful level of ambiguity.”

Spokespeople at Israel’s embassy in Washington and for the White House National Security Council did not respond to requests for comment for this story.

Known Knowns

Experts surveyed by HuffPost this week described three certainties for Israel, the Biden administration and the prospects of limiting Palestinian suffering.

Israel remains determined to pursue Hamas in Rafah beyond the attacks it has already launched on the town — most recently, an airstrike on April 18 that killed 10 members of a family, including five children.

Within Israel, there is popular dissatisfaction with Netanyahu over issues like his failing to bring home Israeli hostages captured in the Hamas-led attack on October 7, that initiated the current fighting. But worsening tensions with Iran could bolster Israelis’ feeling that security should be the country’s top priority.

Tackling the group’s remaining forces in Rafah is “necessary,” argued Neomi Neumann, the former head of research at the Israeli Security Agency, or Shin Bet.

“If we don’t deal with this, Hamas will manage every time to revitalise and become strong — this is the oxygen for Hamas,” said Neumann, now a visiting fellow at the Washington Institute for Near East Policy think tank, referring to Israel’s fears that Hamas will resupply itself through Gaza’s southern border region with Egypt.

Iran is a “danger,” she said, but “at the same time, we need to finish the Gaza issue.”

To “demilitarise the Gaza Strip,” Israel could use non-military means, Neumann noted, like using political agreements and technological safeguards along with Egypt and the US, and bringing in the Palestinian Authority (PA), which governs parts of the occupied West Bank.

Netanyahu and Israeli hardliners see PA rule in Gaza as unacceptable, casting the body as corrupt and Palestinian autonomy in the region as a “reward for terror,” but Neumann called it “the least bad option,” compared to Hamas or direct Israeli control of the strip.

The Biden administration has pinned its hopes on the PA and argues it can be reformed.

There’s a reason to be skeptical of how firm the US will be on the PA and related American plans for the region: its track record.

Throughout his career, and particularly since October 7, Biden has prioritised backing Israel. Critics say this has made him unwilling to deploy US leverage to prevent Israeli violations of human rights and other destabilising actions. But as Israel enters a new level of conflict with Iran — widely seen in American politics as an enemy country — Biden may prove especially deferential to Netanyahu.

“I think the US will have to sit harder on Israel to totally prevent any Rafah invasion,” said Marks of NYU.

The revival of hawkish talk about Tehran since its strike on Israel has already made it “that much harder to push the Israelis toward compliance” with international law “and to create pressure” on aid-related issues, argued the humanitarian organisation source.

“Can the Biden administration and Congress find a way to stop Israel’s war in Gaza and scale a humanitarian response in Gaza while enabling [Israelis] to defend themselves against Iran? Sure, if they properly staffed up and stopped half-measures, they could walk and chew gum,” the source said. “For now, it looks like the latter may take priority over the former.”

But Biden’s oft-stated resistance to a regional conflict could yet convince his team they must halt an Israeli offensive.

“The administration has been pretty consistently holding the line on Rafah because they know it’s a game-changer,” said Matt Duss, the executive vice president of the Center for International Policy think tank. “Biden’s policy has been to try and keep the catastrophe contained within Gaza. It’s an indefensibly callous and dangerous policy, but they’ve been consistent about it.”

Egypt, which worked with Israel to impose a years-long blockade on Gaza, has repeatedly warned Israel and the US about a Rafah assault, fearing it would push Palestinians to cross the Egyptian border en masse. Other US-aligned governments in the region, like Jordan, are facing domestic pro-Palestinian activism that has made some officials worried about the stability of their regimes.

The third reality: Too little humanitarian aid is getting to people who need it in Gaza, and the flow is increasing too slowly, despite some claims of progress.

Israeli authorities have touted an increase in how many trucks of supplies they permitted into Gaza this month through the two currently open crossings into the region, at which Israeli personnel inspect all incoming material.

On Friday, top White House Middle East official Brett McGurk told a public briefing with Jewish Americans there have been “pretty significant changes” in Israel’s treatment of aid — an assessment that was not shared by any of the aid workers HuffPost for this story.

“We’re interested in outputs, not inputs, which to say is the lowering of malnutrition. … We’re interested in no civilian casualties, we’re interested in no indiscriminate bombing. Those are the outputs we’re interested in, and the administration signalled they’re also interested in those things,” said Bill O’Keefe of the charity Catholic Relief Services. “We want to make sure they don’t just get caught up in inputs: there have been some increased trucks, that’s great, but there have been increased trucks before, and then that comes down.”

And on April 9, United Nations spokesperson Jens Laerke told reporters that Israel was counting half-full trucks that enter its screening sites — not the number of repacked, fully-loaded trucks that actually enter Gaza, which aid workers believe to be lower.

Meanwhile, multiple humanitarian officials told HuffPost they have no more details about plans for two additional points for supplying aid to Palestinians — the Erez land crossing and the Ashdod port — two weeks after Netanyahu’s cabinet approved their use.

The road leading from Erez to populated parts of northern Gaza requires extensive repairs before it can be used, and Israel has not greenlighted the opening of another land route, at Karni, Marks said. Meanwhile, Israel’s one currently open crossing into Gaza, Kerem Shalom, is closed on weekends. Calls for increased staffing and screening capacity there have yet to be answered, several aid workers said; neither have appeals for Israel to ease its policy of refusing to let in many aid supplies on the grounds that they’re “dual-use” and could also be used by militants.

Global attention “needs to be not on volume but types of aid and services: Can you get in tubing to do nasal feeding, the right types of food, staff to access clinics?” Marks added. “We still haven’t had that kind of results-based response, as opposed to volume-based.”

Israel could, for instance, make an immediate difference by restarting electricity supplies to Gaza, Paul noted.

Several humanitarian officials also described continued challenges in transporting equipment and personnel to northern Gaza, where famine is already underway.

UNICEF struggled to send fuel and food north from Rafah last week in convoys Ingram participated in, she said, as authorities delayed trucks in holding areas and directed them to a heavily congested route. Israeli officials also maintain extremely limited hours at the checkpoint separating southern Gaza from the north.

“These curfews, we run up against them all the time,” Ingram continued. Once she did reach the north on Sunday, she was appalled: “People were approaching our vehicles, fingers to the mouth. We went to Kamal Adwan hospital, which is treating malnourished children. … It is cruel that this is being inflicted on children when there is food and nutrition treatments and other aid.”

‘Undo Everything’

An Israeli attack on Rafah would force many traumatised Palestinians to abandon what little refuge they have found.

Abood Okal, a Palestinian American who spent weeks in Rafah with his wife and child before being permitted to leave on November 2, told HuffPost his sister Eman, her husband and their three children are now living in the space where the Okals had been staying.

They share a bathroom with 40 other people in a distant family friend’s house and can only communicate with their relatives every 3-4 days, when Eman is able to get a network signal.

Conditions in the other places Palestinians could flee to resemble those where Okal’s other sister, Asma, is staying: in a small tent in Al Mawasi, an overwhelmed coastal community where thousands of families from Rafah may move amid an Israeli offensive. Her children have contracted hepatitis A, one of many diseases that are spreading rapidly in Gaza, and she can only communicate with the outside world around once every two weeks, Okal said.

Soraya Ali of Save the Children, who visited Gaza earlier this month, told HuffPost she saw how people are living beyond Rafah in Deir Al Balah, in central Gaza. She witnessed a makeshift toilet facility shared by 200 people, dozens of people living in “unbearably hot” improvised “tents” crafted from plastic, sticks and tarpaulin and children spending their days roaming the streets seeking food and water.

In Khan Yunis, another town north of Rafah, the streets are full of unexploded bombs and Israeli attacks have destroyed infrastructure that was functioning a few months ago, said Ingram, who visited last week. “It is unrealistic to imagine that somebody could move back there and be safe,” she told HuffPost.

Additionally, people who have been living in Rafah and would now consider moving have already endured overcrowding and shortages of essentials for months. Oxfam’s Alhaddad mentioned one example: She has run out of heart medication for her mother.

“You’re starting already weakened,” O’Keefe said. Relocating civilians, he said, is a matter of providing not just food or shelter (which the Israeli military appears to be working on, by ordering tens of thousands of tents) but also water, sanitation and health equipment.

“We do not see how to safely provide for those people in order to allow for some sort of invasion of Rafah,” he added.

For humanitarian groups, major fighting in Rafah would make providing assistance to Palestinians nearly impossible.

It’s the “only place there is a semblance of an aid response,” Ali said. “If a ground incursion happens in Rafah, it would undo everything.”

Since the start of the war, aid organisations have developed storage and distribution facilities there, as well as accommodations for visiting staff serving Gaza’s population.

Between the added disruption to civilians’ lives and the worsening lack of aid supplies, full-on fighting in Rafah “would be the deadliest chapter of this conflict yet,” Ali said.

Share Button

US House Of Representatives Passes Aid For Ukraine Following Months Of Delay

The House of Representatives approved a $60.8 billion (£49 billion) package of aid for the embattled country of Ukraine on Saturday, ending a months-long attempt by Republicans to leverage the Ukraine money to extract concessions on border security from the White House.

The overwhelmingly bipartisan vote, 311 to 112, was never in doubt even as the path to get to the vote was a long and circuitous one beginning in September of last year.

As in past votes, the final tally was bipartisan, but weighted toward Democrats ― 210 voted in favour, joined by 101 House Republicans. A majority of Republicans, though — 112 — voted against the aid, while no Democrats did.

“This is now up to the American people,” said Representative Mike Quigley (Democrat, Illinois), a co-chair of the bipartisan Congressional Ukraine Caucus, noting that the money should be enough to get Ukraine past the US elections later this year.

“The decision in November will be a decision for Ukraine and Eastern Europe and NATO. That’s the next turning point.”

The bill is one in a four-part, $95 billion (£76.8 billion) package, which also includes $26.4 billion (£21.3 billion) in military aid for Israel and $8.1 billion (£6 billion) for Taiwan and other Asian allies. Another bill in the package also allows for confiscation of official Russian government assets in the US and requires social media app TikTok to divest its US operations from its Chinese owners or face a ban.

It heads now to the Senate, which passed a very similar package without the Russian asset seizure and Tiktok divestiture language, in February. While opponents of the aid to Ukraine are expected to try to delay passage, the Senate vote in February had 70 backers.

President Joe Biden has signalled he will sign the bill once it clears Congress. That would put an end to a fight Republicans picked in late September, when then-House Speaker Kevin McCarthy (Republican, California) jettisoned a smaller $6 billion (£4.85 billion) Ukraine aid package from a stopgap spending bill, choosing to tie its passage to the White House and Democrats agreeing to border security changes.

After a few months’ standoff, Republican Senator James Lankford (Republican, Oklahoma) and Democratic Senator Chris Murphy (Democrat, Connecticut) tried to negotiate a bipartisan deal on Ukraine aid and border security — only to see it fall apart. Republican presidential candidate Donald Trump helped sink the bill by posting his disapproval of it on social media, causing Senate Republicans to balk.

The Senate bill funding Ukraine, Israel and Taiwan aid sat untouched by House Republicans for months — until Iran’s attack on Israel on April 13, which kicked efforts to pass Israel aid back into high gear.

House Speaker Mike Johnson (Republican, Louisiana), who had held off action on Ukraine aid, reversed course on Wednesday, saying, “I would rather send bullets to Ukraine than American boys.”

The vote on Saturday unfolded against the backdrop of that history, and while the outcome was not in doubt, emotions were still raw.

House Democrats on the floor passed out small Ukrainian flags and waved them as the time to vote ticked down. This angered some Republicans who called for the presiding officer to enforce the chamber’s rules of decorum that prohibit literal flag-waving.

The episode also showed that Republicans still believe the border remains a potent political issue.

“We had members of Congress in there waving the Ukrainian flag on the United States House of Representatives floor, while we’re doing nothing to secure our border?” said Representative Marjorie Taylor Greene (Republican, Georgia) “I think every American in this country should be furious.”

Representative Eric Burlison (Republican, Missouri) posted a picture of the Democrats and the flags to social media.

“Democrats waiving Ukrainian flags on the House floor tells you everything you need to know about their priorities,” he wrote. “Ukraine first, America last.”

To get around immigration hardliners within his own party, who opposed advancing the package without a border crackdown, Johnson turned to Democrats to both get it on the House floor and to pass.

That choice to work with them might have major repercussions for the speaker. After the vote to advance the new package bill on Friday, Greene picked up the support of another member, Representative Paul Gosar (Republican, Arizona), for her call for a vote on whether Johnson should remain in the speaker’s chair. With Representative Thomas Massie (Republican, Kentucky), Greene’s group has the numbers to depose Johnson if a vote came and no Democrats supported Johnson.

Greene told reporters on Saturday that she had no immediate plans to force the issue, and hinted that she may simply wait for new party leadership elections after November.

“He’s already a lame duck,” she said of Johnson. “If we had the vote today in our conference, he would not be speaker today.”

On the battlefield, Ukrainian officials have blamed Congress’ delays for recent losses, as Russian attackers have pressed the advantage. In February, Ukraine lost a long-held eastern outpost named Avdiivka, a development the White House blamed directly on an artillery shortage. And Kyiv lost a major power station when it ran out of air defence missiles, according to Ukrainian President Volodymyr Zelenskyy.

The delay may also have sent encouragement to Russian President Vladimir Putin, Democrats say. With the West’s attention drawn to the war between Israel and Hamas in Gaza, Putin has been able to step up the tempo of drone and missile attacks on Ukraine.

Representative Steny Hoyer (Democrat, Maryland) said the final package was essentially the same as what the Senate sent over in February, with the backing of 70 votes there.

“I’m sorry that we didn’t take it up immediately because I think we sent a muddled message to the international community about the resolve that this country had for defending freedom,” he said on Friday.

Share Button

Rihanna Shares The 1 Thing That Helped Her Personal ‘Rediscovery’ After Having Children

Rihanna didn’t have to find love in a hopeless place; instead she found it in her very own closet after adjusting to motherhood.

While speaking with BBC News at the Wednesday launch party of her collaboration with Puma in London, the singer explained how she went through somewhat of a fashion metamorphosis following the birth of her two young sons, RZA and Riot.

“With the first pregnancy, I feel like I was able to wear heels all the way through,” she recalled.

“But then with the second pregnancy, you have a toddler, a belly, it’s winter, you have a coat, a baby bag. You’re like, heels? Hmm, maybe not. That’s why I got a little bit more creative with my comfortable style.”

The Fenty Beauty mogul shared her feelings that she got “too comfortable” in her second pregnancy, with Riot.

“And then I got too comfortable after I had my second kid and I just was in robes, PJs, sweats. And now I’m playing again. Now I’m having fun with my clothes,” she said.

Rihanna and her partner, A$AP Rocky, welcomed their first son, RZA, in May 2022. The “Diamonds” crooner gave birth to Riot in August 2023.

She said getting back to her fashionista vibes in public again has given her “a rediscovery”.

Rihanna donned a sheer black ensemble while attending the Dior show during Paris Fashion Week in March 2022.
Rihanna donned a sheer black ensemble while attending the Dior show during Paris Fashion Week in March 2022.

Edward Berthelot via Getty Images

Now that she’s gotten the hang of motherhood, she said, she’s able to “allow myself that space mentally to approach my closet and create stuff”.

“After a while when you have kids, you think [fashion] is the dumbest… it really is the least important thing,” Rihanna explained. “But it does something for you as a woman, and as a mum, that’s important for us.”

Rihanna notably broke the internet with her stylish, belly-baring maternity ensembles, so it’s totally on-brand that she explained to BBC News why she “refused to buy maternity clothes.”

“I approached it like everything else I approach in fashion,” she said. “I just want to do things my way. I just want to always stitch it up and put my own twist on it.”

“But I just refused to buy maternity clothes, really and truly. I was like, whatever fits was what’s going to work. And that made me challenge myself to get clever with style,” the singer added.

Share Button

Why are we so ill? The working-age health crisis

The number of under 65s struggling with poor health is rising – and it’s a threat to the economy.

Share Button

What do GPs think of Sunak’s sick note plans?

We asked some GPs what they thought of other professionals taking on their responsibility for sick notes.

Share Button

New copper-catalyzed C-H activation strategy

Inspired by what human liver enzymes can do, Scripps Research chemists have developed a new set of copper-catalyzed organic synthesis reactions for building and modifying pharmaceuticals and other molecules. The new reactions are expected to be widely used in drug discovery and optimization, as well as in other chemistry-based industries.

In their study, which initially published in an unedited version on March 28, 2024, in Nature, the chemists showed that their new methods can be used to perform two modifications — called dehydrogenations and lactonizations — on a broad class of inexpensive starting compounds. The reactions require only a simple copper-based catalyst, whereas related reactions typically require much more cumbersome and expensive methods — though this specific type of reaction was previously inaccessible by any organic synthesis method.

“This new two-mode approach could be particularly useful for late-stage modifications and diversifications of natural products and drug molecules,” says study senior author Jin-Quan Yu, PhD, Frank and Bertha Hupp Professor of Chemistry and Bristol Myers Squibb Endowed Chair in Chemistry at Scripps Research.

The study’s first authors were postdoctoral research associate Shupeng Zhou, PhD, and doctoral student Annabel Zhang, PhD, both of the Yu lab during the study.

The initial goal of the research was to find a new and better method for what chemists call carbon-hydrogen (CH) activation, in which a hydrogen atom on the carbon backbone of an organic compound is detached and replaced with something else — a valuable tool for drug synthesis.

In this case, the Yu lab — which has a history of innovations in CH activation chemistry — sought a better way to do CH activations that replace the hydrogen with an oxygen atom. This is a common transformation in the construction or modification of biologically active molecules, though chemists haven’t had laboratory methods for doing it that are as simple, direct and broadly useful as they would like.

Yu and his team looked to nature for inspiration, in particular to cytochrome P450 enzymes, which are found in most living organisms, and help clear potentially toxic molecules in the human liver. Cytochrome P450 enzymes perform oxygen-for-hydrogen reactions very efficiently. Some of these enzymes have the additional ability to catalyze a different hydrogen-removal process called dehydrogenation, which can be used to strip hydrogens from two carbons simultaneously, allowing other atoms — or clusters of atoms — to replace them. The chemists set themselves the ambitious goal of finding a general organic synthesis method for doing either the oxygenation or dehydrogenation reaction, as these versatile “bimodal” enzymes do in living cells.

After months of experimentation, Yu’s team found that, through chemical transformations similar to those done by the bimodal cytochrome P450 enzymes, they could efficiently make compounds called unsaturated primary amides — a class that includes many drug molecules — by dehydrogenating inexpensive starting compounds called methoxyamides. For the catalyst, they needed only copper fluoride — also inexpensive and easy to use.

As the chemists explored the breadth of their new dehydrogenation method using different specific starting compounds, they observed trace amounts of a type of molecule called a lactone, indicating that an oxygenation reaction had occurred. Ultimately, they were able to determine the reaction conditions that favored this oxygenation or “lactonization” over the dehydrogenation. In other words, like the bimodal enzymes that had inspired them, they were able to control whether their approach led down one reaction path or the other.

The team demonstrated the remarkable versatility of this set of reactions by using it to modify — via dehydrogenation or lactonization, or both — a wide variety of starting compounds, including the neurological drug valproic acid and the cholesterol-lowering drug gemfibrozil. (Modifications of existing complex molecules to create potentially better variants are a common drug discovery and optimization technique.)

Yu and his group are currently developing a similar approach for making and modifying lactone- and amide-related compounds called lactams, which include some antibiotics.

“We’ve already had a lot of interest in this new approach from pharma industry chemists,” Yu says.

“Copper-catalyzed dehydrogenation or lactonization of C(sp3)−H bonds” was co-authored by Shupeng Zhou, Zi-Jun Zhang and Jin-Quan Yu.

Support for the research was provided by the National Institutes of Health (2R01GM084019).

Share Button

Gender care review author attacks ‘misinformation’

Dr Hilary Cass says adults who deliberately spread false information are putting young people at risk.

Share Button